Check my Bleach masterpost, there are a few NSFW headcanons for both of them. Some more Grimmie here

Grimmjow

SFW

•The whole feline thing with Grimmjow might be overplayed, but it actually contribtues to a lot of his habits? He gets into scratching fits sometimes. It’s not frantic so to speak, but he does it inadvertently. He scratches his arms or his chest or his neck almost constantly

•He’s also incessantly nervous and anxious. He has a problem. He’s just always hyped up on adrenaline, always on edge. He scratches a lot when the anxiety spikes. Sometimes he scratches himself bloody. When he notices, he just looks at his blood and tsks, almost as if he’s annoyed that he wasn’t more vigilant

•When and if he bathes, it doesn’t matter if it’s hot or cold water. He can throw freezing water on himself just as easily as scorching water. It doesn’t bother him. He thinks being picky about it is unnecessary

•If arrancar need to eat or drink, or maybe, in a modern AU, he’d be addicted to coffee. He takes it black

•Completely random headcanon, but he has this small obsession with moles? He thinks moles on people look very… appealing. He notices it most on humans. Even if he’s not attracted to them, he just thinks it’s interesting. Birthmarks, too. Idk. Just something he notices

•I’m a sucker for human/modern AU of course so I have to go a bit into that. Romanticizing a relationship with Grimmjow is difficult. He’d probably have very unhealthy relationships. Lots of arguments and sneaking around (not necessarily cheating, just a lack of genuine communication) and temper tantrums. The only ‘redeemable’ quality will be that if he’s into you enough to actually be in a relationship with you, he’s obsessed with you. Not always in a scary way, but just like… you’re his. Of course he’s possessive. This might be a fatal flaw though. It likely leads to most of the problems in the relationship, simply because he’s so intense

NSFW

•Clothes are a nuisance when they’re on his partner, but he’s unlikely to ever get fully naked for sex. All he has to do is whip it out. He does prefer his partner’s pants to at least be pulled all the way to their ankles so they’re not in the way. If he doesn’t have time to shove them down their legs, he’ll just rip that shit and go at it. No patience or tact whatsoever

•His stroke game is a little uneven. His thrusts are just so rapid and frantic most of the time that he doesn’t worry about being smooth. You’ll probably be bruised. He can’t slow down even if you tell him to 

Szayel

SFW

•Szayel wouldn’t understand the concept of being in a relationship with someone. I mean, he knows what it entails. But that’s not his mode of operation. If you’re ‘his s/o’, you’re really not. You’re just someone he particularly likes and can tolerate. And he expects you to know that, and not to get ‘involved’ with anyone else

•Szayel is big on praise. Or rather, simply acknowledgement. If you acknowledge his creativity and superior intellect, he’s more likely to treat you kindly

•It’s not difficult to trigger his temper. You’re honestly more likely to do it if you’re his s/o. If you do something stupid, and in his eyes, naive, he just gets irritated. Otherwise, his patience is a lot stronger than most would think

•Szayel with a human s/o won’t work that well. Szayel has a very heavy bias against humans. He thinks they’re inferior and is frankly disgusted by them. They’re good experiments, when it comes down to it. But otherwise, he considers it unnecessary to meddle with them. If he were to have any interest in a human, it would be out of some weird, twisted passion to figure out how they work. Studying human nature/anatomy kind of thing

•You’ll know Szayel is relatively genuine with you (as genuine as he can be) if he doesn’t smile at you. He gives people this fake, sly smile when he wants something from them, or if he’s persisting with a facade. But if he likes you, there aren’t any fabricated smiles. It seems a little daunting, but it’s impressive if you get that far with him tbh

•Low key obsessed with cleanliness. As soon as he starts getting peeved with a mess, he has to clean up and get rid of it. He likes his workspace to be spotless. If you’re his potential ‘s/o’, be prepared to face his temper if you’re being messy. Even if in his eyes, ‘messy’ is just having a t shirt lying around on the floor. One t shirt. That’s all it takes

NSFW

•Doesn’t like sex being messy. You’d think he might, but no. Still about the cleanliness. Honestly, sex to him is not important, and a little trivial. The most he’ll indulge is seeing his partner’s cum

•Sex will be once a week or every few weeks. Whenever he has the time, and whenever he needs to just take his partner and use them. That’s probably what he considers it, using them. He has a habit of chasing his own orgasm and not paying much attention to his partner’s

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